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Tinh dầu Cade rectified

Cade Rectified

Juniperus oxycedrus L.

BaseGỗ

Gỗ cổ thụ âm ỉ than tàn, khói da thuộc sẫm tối, nhựa cháy sém bên than đỏ, khô khan nguyên thủy, tối trầm như hơi thở tổ tiên

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Tóm Tắt Khoa Học

Từ Thư Viện Kinh Điển
  1. Juniperus oxycedrus L. (Cupressaceae) — wood, by destructive distillation (pyrolysis-tar class, same class as [[birch-tar]] — only 2 such oils in B216). Plant = prickly juniper; oil name = cade (synonym: juniper tar). This file covers the rectified (purified) form only; for the crude form see [[cade-unrectified]] (distinct safety class + IFRA regulatory status).
  2. IFRA permitted with PAH cap. IFRA 2009: rectified cade may be used as fragrance ingredient only if final product (alone or combined with [[birch-tar]]) contains ≤1 ppb total PAHs (benzo[a]pyrene + 1,2-benzanthracene). Rectified benzo[a]pyrene residual up to 20 ppb in the oil itself — "less than the concentration found in some foodstuffs" (Bouhlal 1988a).
  3. T&Y hazards: Toxicity. Contraindications: "Should not be taken in oral doses." Non-phototoxic (Opdyke 1975 p.733–734); 2% on 25 volunteers non-irritating + non-sensitizing; 3% = 2 mild irritation reactions in 25 volunteers (Bouhlal 1988a). Acute oral LD50 rats 8.0 g/kg (Jenner 1964), ≥5 g/kg (alternate); dermal LD50 rabbits >5 g/kg.
  4. Chemistry (rectified, Abisset 2004): δ-cadinene 24.2% + torreyol+3 alcohols 9.3% + epicubenol 8.7% + zonarene 8.1% + β-caryophyllene 6.1% + (E)-calamenene 5.1% + α-caryophyllene 4.3% + 14-hydroxy-α-caryophyllene 2.8%. Sesquiterpene-hydrocarbon-dominant post-rectification — PAHs + volatile phenolics largely removed (benzo[a]pyrene residual ~20 ppb vs 8,000 ppb in [[cade-unrectified]]).
  5. Destructive-distillation pyrolysate rail (CLASS-LEVEL): Wood burns during distillation → PAH formation same mechanism as cigarette smoke + charred food. Not a steam-distilled oil — safety profile fundamentally different from all other juniper oils ([[juniper-berry]], [[juniper-needle]] = J. communis steam distillate; [[cedarwood-virginian]] = J. virginiana heartwood steam distillate). Do NOT extrapolate.
🌿
Thận trọngNốt BaseSmoky-leathery-tarry-woody-phenolic

Cade Rectified

Tinh dầu Cade rectified (Juniper tar, đã tinh chế)

Juniperus oxycedrus L.

Tinh dầu Cade rectified (Juniper tar, đã tinh chế) — Smoky-leathery-tarry-woody-phenolic

⚠️Tinh dầu này cần thận trọng khi sử dụng. Đọc kỹ hướng dẫn an toàn.

Tổng Quan

Danh pháp khoa học
Juniperus oxycedrus L.
Họ thực vật
Cupressaceae
Bộ phận dùng
Wood
Phương pháp chiết xuất
destructive_distillation
Màu sắc
Phân loại nốt hương
Nốt Base
Hương thơm
Chemotype / Cultivar

Tình trạng tại Việt Nam

Xem chi tiết

Phân loại nốt
Base
Cường độ
4/5
Độ bền trên da
2–4 giờ
Họ hương
Smoky-leathery-tarry-woody-phenolic
Hương đầu (Opening)(0–15 phút)

Smoldering ancient timber, dark leathery smoke, charred resinous ember, dry and primal woodsmoke, muted ancestral darkness

Hương giữa (Heart)(15–60 phút)

Gỗ cổ thụ âm ỉ than tàn, khói da thuộc sẫm tối, nhựa cháy sém bên than đỏ, khô khan nguyên thủy, tối trầm như hơi thở tổ tiên

Hương nền (Drydown)(1–4 giờ)

2–4 giờ

Cường độ hương
4/5
Da khô
2/5

Da dầu/mụn
2/5

Da lão hóa
2/5

Da thường
1/5

Da nhạy cảm
1/5

Da hỗn hợp
2/5

Nhập khẩuImported

Tên gọi tại Việt Nam

Tinh dầu Cade rectified (Juniper tar, đã tinh chế)

Pha Chế & Hòa Hợp

Antipruritic

Phenolic constituents (guaiacol, cresols) in rectified cade are thought to reduce itch signaling at the cutaneous level, consistent with traditional dermatological use in psoriasis and chronic eczema.

Ref: Tisserand & Young 2014, Ch.13 p.486–487

Antimicrobial — broad-spectrum cutaneous

Guaiacol, cresols, and cadinene fractions contribute antimicrobial activity against skin-surface pathogens, supporting traditional use in infected dermatoses.

Ref: Opdyke, D.L.J. (1975) Food and Cosmetics Toxicology 13, p.733–734

Keratolytic

Tar-derived phenols promote controlled desquamation of hyperkeratotic skin layers; rectified cade retains this property while substantially reducing PAH load relative to unrectified grade.

Ref: Tisserand & Young 2014, Ch.13 p.486–487

Antiparasitic (ectoparasites)

Cytotoxic phenolic fractions disrupt the cuticle and neuromuscular function of ectoparasites (lice, Sarcoptes scabiei), consistent with centuries of veterinary and human antiparasitic use.

Ref: Tisserand & Young 2014, Ch.13 p.486–487

Anti-inflammatory — cutaneous

Sesquiterpene cadinene fractions may modulate local cutaneous inflammation; evidence is preclinical and class-extrapolated rather than demonstrated specifically for rectified cade.

Ref: class-extrapolation from juniper berry (Juniperus communis)

AI-summary

No modern RCT-grade clinical evidence exists for rectified cade EO specifically. Opdyke (1975) conducted acute oral LD50 and dermal irritation testing in animals. Bouhlal et al (1988a) performed volunteer patch testing confirming tolerance only at very low concentrations. Phillips et al (1990) and Schoket et al (1990) documented genotoxicity and DNA adduct formation at the tar class level (PAH-driven), establishing the mechanistic rationale for the strict 0.1% dermal cap even after rectification. Traditional dermatology used unrectified cade for psoriasis and eczema, but those outcomes are not directly transferable to the rectified EO grade. Summary: traditional dermatological use well-documented; no RCT evidence for rectified cade EO.

Narrative

Tâm trạng: Grounding, Balancing

groundingancestralintrospectionresilienceprotectionmelancholy

Chakra

root

Ngũ hành

thuy

Phương phápLiều lượngGhi chú
Topical spot application0.1% in carrier oil (1 drop per 20 ml)Hard maximum: 0.1% adult dermal cap (T&Y 2014). Affected skin only — psoriasis plaques, eczema. Avoid face and mucous membranes. Never undiluted. Contraindicated in pregnancy and children.
Medicated scalp treatment0.1% in shampoo base or jojoba (1 drop per 20 ml)Rinse-off reduces systemic absorption. Leave-on must not exceed 0.1%. For seborrheic dermatitis and scalp psoriasis in adults only. Patch test required before first use.
Compress (localized)0.1% in warm water with dispersantWarm compress over affected skin plaques only. Limit application area. Contraindicated in pregnancy; not for children. Wash hands immediately after contact with preparation.
Diffusion (atmospheric only)1–2 drops maximum in 100 ml waterSmoky, tarry, phenolic aroma. Very low volumes only. Not for direct therapeutic inhalation. Avoid spaces shared with pregnant women or children due to absolute contraindications.

Dầu nền phù hợp

JojobaLiquid wax, exceptionally stable, non-comedogenic; ideal scalp vehicle for precise medicinal dilutions at the 0.1% hard cap.
Hemp seed oilRich in linoleic and gamma-linolenic acid; anti-inflammatory fatty acid profile complements cade's keratolytic use in eczema and psoriasis.
Argan oilHigh oleic and linoleic content with tocopherols; stable carrier supporting skin barrier repair alongside cade's keratolytic activity in chronic dermatoses.

Kết hợp tốt với

ResinousEarthySpicyWoody

Blend kinh điển

[Tisserand & Young] Ch.13 p.486–487 (Cade rectified)
[IFRA] cade oil + PAH restrictions
[Opdyke, D.L.J.] 734 — rectified acute + dermal testing
[Abisset] private communication, rectified chemistry
[Jenner, P.M. et al] acute oral LD50
[Bouhlal, K. et al] volunteer irritation testing + PAH context
[Phillips, D.H. et al] genotoxicity in excised human skin (tar class)
[Schoket, B. et al] DNA adducts in patients receiving tar therapy (tar class)
[Budavari, S.] benzo[a]pyrene carcinogen reference

An Toàn

Giới hạn da tối đa

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Giới hạn IFRA

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Thai kỳ & Cho con bú

Tam cá nguyệt 1Unknown
Tam cá nguyệt 2Unknown
Tam cá nguyệt 3Unknown

Giới hạn độ tuổi

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Bảo quản

Bảo quản nơi tối, mát

Thông tin chỉ mang tính tham khảo, không thay thế tư vấn y tế chuyên nghiệp. SYMELab v2.0

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Hồ Sơ Hoá Học Chi Tiết
§3 Chemical Profile — chemotype, constituent ranges, adulteration

Rectified cade — Abisset 2004

Constituent%
δ-Cadinene24.2%
Torreyol (+ 3 other alcohols)9.3%
Epicubenol8.7%
Zonarene8.1%
β-Caryophyllene6.1%
(E)-Calamenene5.1%
α-Caryophyllene4.3%
14-Hydroxy-α-caryophyllene2.8%
α-Calacorene2.3%
α-Muurolene2.3%
Cadalene1.3%
α-Selinene1.2%
14-Oxo-α-caryophyllene1.1%
14-Hydroxy-δ-cadinene1.0%
Gleenol0.4%
Benzo[a]pyrene (PAH, residual)≤20 ppb

Characterized total ~78.2% — sesquiterpene-dominant profile post-rectification. Rectification removes most PAHs + volatile phenolics (cresols, guaiacol, phenol present in crude — see [[cade-unrectified]]).

Chemistry insights

  • Sesquiterpene hydrocarbon base: δ-cadinene + cadinane-class sesquiterpenes dominate — woody-smoky signature with tar softened by rectification. Fundamentally different from steam-distilled junipers ([[juniper-berry]], [[juniper-needle]]) which are α-pinene/myrcene/sabinene monoterpene-dominant.
  • Residual PAH (benzo[a]pyrene ≤20 ppb): IARC Group 1 human carcinogen (Budavari 1989). "Less than the concentration found in some foodstuffs" per Bouhlal 1988a — food PAH exposure includes grilled + smoked foods. IFRA final-product cap 1 ppb addresses the cosmetic exposure pathway.
  • Rectification efficacy: Removes ~99.75% of benzo[a]pyrene from crude (8,000 ppb → ≤20 ppb) + most phenolics (cresols, guaiacol, phenol down to trace). But does NOT produce a "clean" oil — residuals still present.
  • Olfactory: Dense smoky-leathery-tarry-woody-medicinal with some phenolic softening vs crude. Historical use in smoky fougère + chypre + leather accords.
Công Dụng Trị Liệu Chi Tiết
§10 Therapeutic Uses — skin, emotional, physical, respiratory
  • Modern aromatherapy: Largely discontinued due to PAH concerns. Not recommended for new practitioners; PAH-reduced synthetics preferred for smoky-accord perfumery use.
  • Dermatology (historical): Rectified cade was historically used in dermatological tar preparations for psoriasis + eczema at trace dilution. Modern dermatology moving to refined cleaner-profile tar substitutes given carcinogenicity concerns (Phillips 1990 + Schoket 1990 demonstrated DNA adducts in skin even for non-cade coal-tar preparations).
  • Perfumery (restricted): Smoky + leathery base accent, trace dosage only under IFRA.
  • Veterinary (historical): Topical wound + parasite care. Modern practice moving away.
Năng Lượng & Ngũ Hành
§11 Energetics — TCM, Ayurveda, aromatic energetics
  • Five-element: Hỏa-Kim (Fire–Metal — fire-born pyrolysate + metal-astringent phenolic character).
  • Not a standard Mojay materia medica entry (declining use due to safety profile).
  • Yang-intense, harsh-cleansing — traditional framing reflects cautery-like historical topical use. Modern safety ethics counsel restraint.

Dữ Liệu Kỹ Thuật Y Khoa

§14 Renderer Contract — Tisserand & Young V2.2

Thông Số Định Lượng

hazards
["toxicity_residual_pah","residual_pah_carcinogenicity","oral_contraindicated"]
phototoxic
false
safety_level
caution
cap_derivation
ifra_pah_1ppb_final_product_derived_practical_limit
oxidation_risk
low_medium
drug_interactions
[]
shelf_life_months
18
max_dilution_adult
0.1
contraindicated_all
false
max_dilution_elderly
0
max_oral_dose_mg_day
0
max_dilution_child_2_6
0
max_dilution_sensitive
0
max_dilution_adult_face
0
max_dilution_child_6_12
0
contraindicated_children
true
contraindicated_pregnancy
true
max_dilution_child_under2
0
max_dilution_pregnancy_1st
0
max_dilution_pregnancy_2nd
0
max_dilution_pregnancy_3rd
0

Tài Liệu Y Khoa Tham Khảo

  • Tisserand & Young (2014) Essential Oil Safety 2nd ed — Ch.13 p.486–487 (Cade rectified)
  • IFRA (2009) Code of Practice — cade oil + PAH restrictions
  • Opdyke, D.L.J. (1975) Food and Cosmetics Toxicology 13, p.733–734 — rectified acute + dermal testing
  • Abisset (2004) — private communication, rectified chemistry
  • Jenner, P.M. et al (1964) — acute oral LD50
  • Bouhlal, K. et al (1988a) — volunteer irritation testing + PAH context
  • Phillips, D.H. et al (1990) — genotoxicity in excised human skin (tar class)
  • Schoket, B. et al (1990) — DNA adducts in patients receiving tar therapy (tar class)
  • Budavari, S. (1989) Merck Index — benzo[a]pyrene carcinogen reference