SYMELab
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Cánh kiến trắng

Benzoin

Styrax benzoin Dryand. / Styrax paralleloneurus Perkins / Styrax tonkinensis Pierre

BaseNhựa thơm

Nhựa balsam ấm áp ngọt ngào, hổ phách ủ hương vani, khói nhựa linh thiêng nhẹ thoảng, chiều sâu gỗ-nhựa bao bọc, ấm nồng lắng đọng

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Tóm Tắt Khoa Học

Từ Thư Viện Kinh Điển
  1. CRITICAL category rail: Benzoin is a RESINOID, NOT an essential oil. T&Y explicit: "There is no benzoin essential oil." Commercial "benzoin oil" is a solvent-extracted resinoid, typically diluted 50% in a carrier (benzyl alcohol, benzyl benzoate, DPG, or — in older products — diethyl phthalate). Must never be described or catalogued as a steam-distilled EO.
  2. Dual-source rail (same product, two countries, three species): Sumatra benzoin from Styrax benzoin Dryand. + S. paralleloneurus Perkins (Indonesia). Siam benzoin from S. tonkinensis Pierre (primarily Laos — Luang Prabang — + Cambodia + southern China; the trade name "Siam" is historical from the old Thai market hub, not geographic origin of production today). Family Styracaceae.
  3. Sumatra volatile profile (Moyler 1998): Benzyl benzoate 50.7% + benzyl alcohol 43.4% + (Z)-cinnamyl (E)-cinnamate 1.5% + cinnamic acid 1.4% + ethyl cinnamate 1.0% + benzoic acid 0.1%. Siam volatile profile: Benzyl benzoate 39.3% + benzyl alcohol 38.8% + benzoic acid 18.4% + ethyl cinnamate 0.8%. Key discriminator: Siam carries ~18% benzoic acid, Sumatra only 0.1% — this changes the oral dose limit and the sensitization class significantly.
  4. Hazards: Skin sensitization low risk (but Peru-balsam cross-reaction in sensitized patients up to 80% per Hjorth 1961). Cautions dermal: hypersensitive/diseased/damaged skin + children <2y. Max oral 368 mg (JECFA 5 mg/kg benzoic acid equivalents ADI — mostly the Siam rail). Max dermal 2% best-practice; CIR 5% cosmetic safe (Nair 2001a).
  5. Coniferyl benzoate 75%-of-raw-gum rail: Raw gum contains coniferyl benzoate up to 75% (NON-volatile, does NOT transfer to the resinoid/absolute/solvent-extract). Listed as sensitization candidate in older literature but is absent from the commercial product. Do not flag coniferyl benzoate on the commercial slug.
🌿
Thận trọngNốt BaseSweet-balsamic

Benzoin

Cánh kiến trắng (Benzoin resinoid — Sumatra / Xiêm)

Styrax benzoin Dryand. / Styrax paralleloneurus Perkins / Styrax tonkinensis Pierre

Cánh kiến trắng (Benzoin resinoid — Sumatra / Xiêm) — Sweet-balsamic

⚠️Tinh dầu này cần thận trọng khi sử dụng. Đọc kỹ hướng dẫn an toàn.

Tổng Quan

Danh pháp khoa học
Styrax benzoin Dryand. / Styrax paralleloneurus Perkins / Styrax tonkinensis Pierre
Họ thực vật
Styracaceae
Bộ phận dùng
Phương pháp chiết xuất
solvent_extraction_resinoid
Màu sắc
Phân loại nốt hương
Nốt Base
Hương thơm
Chemotype / Cultivar

Tình trạng tại Việt Nam

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Phân loại nốt
Base
Cường độ
3/5
Độ bền trên da
2–4 giờ
Họ hương
Sweet-balsamic
Hương đầu (Opening)(0–15 phút)

Warm honeyed balsam, vanilla-kissed amber resin, softly smoky sacred incense, enveloping sweet-woody depth, tenacious fixative warmth

Hương giữa (Heart)(15–60 phút)

Nhựa balsam ấm áp ngọt ngào, hổ phách ủ hương vani, khói nhựa linh thiêng nhẹ thoảng, chiều sâu gỗ-nhựa bao bọc, ấm nồng lắng đọng

Hương nền (Drydown)(1–4 giờ)

2–4 giờ

Cường độ hương
3/5
Da khô
5/5

Da dầu/mụn
1/5

Da lão hóa
4/5

Da thường
3/5

Da nhạy cảm
1/5

Da hỗn hợp
2/5

Nhập khẩuImported

Tên gọi tại Việt Nam

Cánh kiến trắng (Benzoin resinoid — Sumatra / Xiêm)

Pha Chế & Hòa Hợp

Vulnerary — minor wound healing

Benzyl benzoate and benzoic acid constituents form a mild antiseptic, film-forming barrier over minor cuts and chapped skin, supporting re-epithelialization in traditional practice.

Ref: Tisserand & Young 2014, Ch.13 Benzoin

Emollient — skin-softening

The resinoid's wax-ester matrix creates an occlusive film that locks in moisture and softens roughened or cracked skin surfaces, classic use for dry/cracked heels.

Ref: Tisserand & Young 2014, Ch.13 Benzoin

Expectorant — upper respiratory

Inhaled benzoic acid vapors stimulate bronchial mucosal secretion and promote expectoration; compound benzoin tincture holds pharmacopoeial history for this indication.

Ref: Tisserand & Young 2014, Ch.13 Benzoin

Antimicrobial — preservative

Benzoic acid, the primary constituent, disrupts microbial membrane integrity across a broad spectrum of bacteria and yeasts at physiologically relevant concentrations.

Ref: JECFA 1996 group ADI benzoic acid equivalents; Nair (CIR) 2001a

Anxiolytic — emotional comfort

Sweet vanillin-rich olfactory profile modulates limbic system activity via the olfactory–amygdala pathway; traditionally used in aromatherapy for grief, anxiety, and emotional exhaustion.

Ref: Tisserand & Young 2014, Ch.13 Benzoin; traditional aromatherapy use

Anti-inflammatory — topical

Cinnamic acid esters (benzyl cinnamate, ethyl cinnamate) are proposed to modulate arachidonic acid pathway mediators in skin tissue; mechanism class-extrapolated from Peru balsam chemistry overlap.

Ref: class-extrapolation from Peru balsam (Hjorth 1961 cross-reactivity implies shared active chemistry)

AI-summary

No RCT-grade therapeutic trial evidence identified in available citations. CIR Expert Panel (Nair 2001a) reviewed benzoin at 5% in cosmetic formulations and concluded it safe for cosmetic use. NTP (1980) 104-week rat/mouse feeding study found no carcinogenicity signal. In-vitro mutagenicity flags (Oberly 1993 MLA; Ishidate 1988 CHL chromosomal aberration positive) were interpreted as likely false-positive artefacts under specific test conditions by Kirkland (2005). Contact sensitization evidence is substantial: Hjorth (1961) documented 80% cross-reaction with Peru balsam; Scardamaglia (2003) found 9.2% positive patch test (45/477) to compound tincture of benzoin in a clinical dermatology cohort; Sharp (1978) confirmed sensitizing potential in guinea pig challenge assay. Collectively these data support cautious low-concentration topical use with mandatory patch testing rather than therapeutic endorsement at elevated concentrations.

Narrative

Tâm trạng: Calming, Grounding

comfortanxietywarmthsecuritymelancholynostalgia

Chakra

sacral

Ngũ hành

tho

Phương phápLiều lượngGhi chú
Diffusion2-3 drops per 100ml waterWarm balsamic-vanilla profile suits evening emotional support blends. Viscous resinoid may need gentle warming (max 40°C) before dispensing. Blend with frankincense or sandalwood.
Topical massage0.5-2.0% in carrier oilADULTS ONLY (children contraindicated). Never exceed 2.0% max dermal. Mandatory patch test — 80% Peru-balsam cross-reaction risk (Hjorth 1961). Prefer jojoba or sweet almond carrier.
Skincare — targeted application0.5-1.5% in lotion or balmTraditional use for cracked heels, roughened skin, minor superficial healing. Avoid broken or actively sensitized skin. Occlusive base such as shea butter amplifies emollient effect.
Steam inhalation1-2 drops in hot (not boiling) water5-10 min session for respiratory congestion support. Adults only — contraindicated in children. Avoid in asthma without professional guidance. Cover head, keep eyes closed.

Dầu nền phù hợp

JojobaNon-comedogenic wax ester is chemically stable and disperses the heavy resinoid cleanly; low intrinsic sensitization risk is important given benzoin's elevated contact-sensitization profile.
Sweet almond oilTraditional pairing for skin-soothing and emollient blends; mild oleic-acid base enhances benzoin's skin-softening action on dry or mature skin types.
Fractionated coconut oilLightweight, near-indefinite shelf life, and good skin penetration facilitate even distribution at the 2.0% dermal cap without excessive occlusion on combination skin.
Shea butter (refined)Rich occlusive base ideal for cracked-heel and dry-skin formulations; stearic/oleic dominant profile complements benzoin's film-forming vulnerary action.

Kết hợp tốt với

FloralWoodySpicyEarthy

Blend kinh điển

[Tisserand & Young] Ch.13 Benzoin profile
[Moyler] Sumatra + Siam volatile profiles [via B216]
[Hjorth] Peru-balsam cross-reaction 80% [via B216]
[Sharp] guinea pig 10% challenge sensitizing [via B216]
[Scardamaglia] 45/477 (9.2%) positive compound tincture benzoin [via B216]
[Nair] CIR 5% cosmetic safe [via B216]
[JECFA] group ADI 0–5 mg/kg benzoic acid equivalents [via B216]
[Burfield] adulteration (benzoic acid / benzyl cinnamate / ethyl cinnamate / vanillin) [via B216]
[Oberly] MLA mutagenic [via B216]
[Ishidate] CHL CA positive [via B216]
[Kirkland] false-positive signal interpretation [via B216]
[NTP] 104-week rat/mouse feeding no carcinogenicity [via B216]

An Toàn

Giới hạn da tối đa

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Giới hạn IFRA

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Thai kỳ & Cho con bú

Tam cá nguyệt 1Unknown
Tam cá nguyệt 2Unknown
Tam cá nguyệt 3Unknown

Giới hạn độ tuổi

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Bảo quản

Bảo quản nơi tối, mát

Thông tin chỉ mang tính tham khảo, không thay thế tư vấn y tế chuyên nghiệp. SYMELab v2.0

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Hồ Sơ Hoá Học Chi Tiết
§3 Chemical Profile — chemotype, constituent ranges, adulteration

Sumatra (S. benzoin + S. paralleloneurus)

Constituent%
Benzyl benzoate50.7%
Benzyl alcohol43.4%
(Z)-Cinnamyl (E)-cinnamate1.5%
Cinnamic acid1.4%
Ethyl cinnamate1.0%
Benzoic acid0.1%

Siam (S. tonkinensis)

Constituent%
Benzyl benzoate39.3%
Benzyl alcohol38.8%
Benzoic acid18.4%
Ethyl cinnamate0.8%

Chemistry insight:

  • Both sources are benzyl-ester-dominant (benzyl benzoate + benzyl alcohol ≈ 78–94% combined) — highly fixative, sweet-balsamic-vanillic.
  • Key species discriminator: Siam contains 18.4% benzoic acid (vs 0.1% Sumatra) — this drives the JECFA ADI oral limit (5 mg/kg benzoic acid equivalents) for Siam much more than for Sumatra. Max oral 368 mg is calibrated on Siam.
  • (Z)-Cinnamyl (E)-cinnamate is a Sumatra-only minor marker (1.5%) — authentication signal for Sumatra vs Siam.
  • Coniferyl benzoate appears at up to 75% in the RAW gum per classical literature but is NON-volatile and does NOT survive into the resinoid / absolute / solvent extract. Therefore do NOT carry it into the commercial safety profile as if it were in the product.
  • Quality / adulteration (Burfield 2003): added benzoic acid, benzyl cinnamate, ethyl cinnamate, or vanillin are common adulterants.
Công Dụng Trị Liệu Chi Tiết
§10 Therapeutic Uses — skin, emotional, physical, respiratory
  • Friar's Balsam / Compound Benzoin Tincture: Classical pharmacopeial respiratory steam inhalation (bronchitis, laryngitis, catarrh) — typically 5 mL in a bowl of hot water, covered head, inhale. But Scardamaglia 2003 9.2% positive rate in contact dermatitis clinic raises caution for repeated clinical exposure (nurses applying it to wounds / bandage fixation are a known sensitization group).
  • Fixative in oriental / amber / vanilla blends: 0.5–2% in carrier.
  • Skin-care for dry / chapped / mature skin: 1–2% in carrier, not on damaged skin.
  • Incense: Direct charcoal or beeswax-mixed.
  • Oral flavoring: Limited to JECFA ADI (5 mg/kg benzoic acid equivalents) — primarily a Siam constraint.
Năng Lượng & Ngũ Hành
§11 Energetics — TCM, Ayurveda, aromatic energetics
  • Five-element: Thổ (Earth — warming, grounding) + Hỏa (Fire — circulation, through cinnamic acid micro-warming).
  • TCM: An-xi-xiang (安息香 — "peaceful-rest resin") — historically used in ritual incense, reported to open the orifices and pacify the spirit. Listed as a materia medica for obstructed-orifice patterns.
  • Classical Western herbal: Friar's balsam (compound benzoin tincture) — respiratory steam, topical wound antiseptic, bandage fixative.
  • Eastern Orthodox / Catholic liturgical incense (component of some formulations).

Dữ Liệu Kỹ Thuật Y Khoa

§14 Renderer Contract — Tisserand & Young V2.2

Thông Số Định Lượng

hazards
["skin_sensitization_low_population_risk","peru_balsam_cross_reaction_80pct"]
phototoxic
false
is_essential_oil
false
product_category
resinoid
drug_interactions
[]
photoallergy_risk
commercial_diluents
["benzyl_alcohol","benzyl_benzoate","DPG","diethyl_phthalate_older"]
max_dilution_elderly
2
max_oral_dose_mg_day
368
max_dilution_child_2_6
1
max_dilution_adult_face
1.5
max_dilution_child_6_12
2
acute_oral_ld50_rat_g_kg
contraindicated_pregnancy
false
max_dilution_child_under2
max_dilution_adult_general
2
max_dilution_breastfeeding
2
max_dilution_pregnancy_1st
1.5
max_dilution_pregnancy_2nd
2
max_dilution_pregnancy_3rd
2
acute_dermal_ld50_rabbit_g_kg
contraindicated_breastfeeding
false
max_oral_dose_mg_day_pregnancy
200
commercial_dilution_typical_pct
50
contraindicated_children_under2
true

Luận Giải Văn Cảnh

source_types

{'sumatra': ['Styrax benzoin', 'Styrax paralleloneurus'], 'siam': ['Styrax tonkinensis']}

distinct_from

liquidambar_orientalisliquidambar_styraciflua

dermal_cautions

hypersensitive_skindiseased_skindamaged_skinchildren_under_2y

is_essential_oil

product_category

'resinoid' (or 'absolute' for solvent-absolute variant)

extraction_method

solvent_extraction_resinoid

known_adulterants

benzoic_acidbenzyl_cinnamateethyl_cinnamatevanillin

max_oral_dose_mg_day

368

oral_limit_rationale

JECFA_benzoic_acid_equivalents_ADI_5_mg_kg

carcinogenicity_status

negative_rodent_bioassay

cross_reactive_allergens

peru_balsamfragrance_mixcolophonytea_tree

raw_gum_only_constituents

coniferyl_benzoate

type_distinguishing_marker

'benzoic_acid_content' (Sumatra 0

mutagenicity_invitro_signal

equivocal_likely_false_positive

occupational_exposure_caution

nurses_wound_care_bandage_fixation

commercial_product_constituents

benzyl_benzoatebenzyl_alcoholbenzoic_acidethyl_cinnamatecinnamic_acid

clinical_sensitization_prevalence

0

cross_reactivity_rate_peru_balsam

0

Tài Liệu Y Khoa Tham Khảo

  • Tisserand & Young (2014) Essential Oil Safety 2nd ed — Ch.13 Benzoin profile
  • Moyler (1998) — Sumatra + Siam volatile profiles [via B216]
  • Hjorth (1961) — Peru-balsam cross-reaction 80% [via B216]
  • Sharp (1978) — guinea pig 10% challenge sensitizing [via B216]
  • Scardamaglia (2003) — 45/477 (9.2%) positive compound tincture benzoin [via B216]
  • Nair (2001a) — CIR 5% cosmetic safe [via B216]
  • JECFA (1996) — group ADI 0–5 mg/kg benzoic acid equivalents [via B216]
  • Burfield (2003) — adulteration (benzoic acid / benzyl cinnamate / ethyl cinnamate / vanillin) [via B216]
  • Oberly (1993) — MLA mutagenic [via B216]
  • Ishidate (1988) — CHL CA positive [via B216]
  • Kirkland (2005) — false-positive signal interpretation [via B216]
  • NTP (1980) — 104-week rat/mouse feeding no carcinogenicity [via B216]